New amino-ketoxime derivatives: Synthesis and Characterization

Abstract

This study describes synthesis and characterization of new aminoketoximes in detail. Firstly, 4,4'-bis(chloroacetyl)diphenylmethane and 4,4'-bis(chloroacetyl)diphenylether were synthesized by reaction of diphenylmethane and diphenylether with chloroacetyl chloride, respectively. Then, 4,4'-bis(chloroacetyl)diphenylmethane and 4,4'-bis(chloroacetyl)diphenylether were converted to 4,4'-methylenebis(phenylglyoxylohydroximoylchloride)  and 4,4'-oxybis(phenylglyoxylohydroximoylchloride) by using HCl gas and butyl nitrite. New aminoketoxime derivatives were then obtained by using the synthesized chloroketoxime derivatives with 9-ethyl-3-aminocarbazole and 4-amino-N-phenylaniline.  All of the obtained products were characterized by combination of FT-IR, ¹H NMR, ¹³C NMR and elemental analysis.